for i, rows in df.iterrows():
    x, y = df.iloc[rows].copy(), df.iloc[rows+1].copy()
    df.iloc[rows], df.iloc[rows+1] = y, x
    break

I get error on execution:

positional indexers are out-of-bounds`

My code in Spyder Complete code with operations to be performed after each swap

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Use iloc with:

print(df.iloc[[a for b in zip(df.index[::2][::-1],df.index[1::2][::-1]) for a in b]][::-1])