Itemsource is binded to a list of string(numbers without decimal points) Display ComboBoxEdit values as 4 point decimal number : here is the sample code
<dxe:ComboBoxEdit x:Name="Stop"
Grid.Column="2"
Width="250"
Margin="0,6,5,15"
HorizontalAlignment="Right"
ItemsSource="{Binding CurrentJobItem.ScanSettings[0].StopCollection}"
IsTextEditable="True"
AutoComplete="True"
IncrementalFiltering="True"
ImmediatePopup="True"
EditValue="{Binding CurrentJobItem.ScanSettings[0].Stop, UpdateSourceTrigger=LostFocus,
Converter={StaticResource JobSettingConverter}}"
PreviewTextInput="NumberValidationComboBox"
InputScope="Number"
Validate="TextEditMaterialValidate">
<dxe:ComboBoxEdit.ItemTemplate>
<DataTemplate>
<TextBlock Text="{Binding StringFormat={}{0:0000}}" />
</DataTemplate>
</dxe:ComboBoxEdit.ItemTemplate>
</dxe:ComboBoxEdit>