I have data stored in CSV format.The data contains numerical values formatted as text but written without any apostrophe.
I've tried to export the data using xlsread, bu Matlab automatically remove the leading zero. Is it possible to force Matlab to read it as string to keep the leading zero?

xlsread has three outputs, the third bering the raw data. Use the third output, you will find the text there. Then you can convert the text to numeric data using str2num.